Carbon nanotubes are a novel form of pure carbon. CNTs are formed by rolling graphite sheets, with an inner diameter starting from 0.5 nm and reaching several nm, and a length that ranges from a few ìm to several hundreds of ìm. Tubes formed by only one single graphite layer are called single-wall nanotubes (SWNT). Tubes consisting of multiple concentric graphite layers are called multi-wall nanotubes (MWNT).
Properties of Single-Wall Carbon Nanotubes
The diameter of SWNTs varies from 0.4 to 3 nm. The helicity of
the nanotubes is usually described by the Hamada vector, which
indicates how the graphene sheet is rolled up along a lattice
vector with components (n, m). The values of the integers n and
m identify the general geometry of SWNT. Tubes with n=m are named
"armchair"; tubes with either n=0 or m=0 are named "zigzag"; all
others have chiral symmetry. SWNTs tend to agglomerate and form
bundles of several tens of nanotubes. SWNTs are quite stiff and
exceptionally strong, which translates to high Young's modulus
and high tensile strength.
Properties of Multi-Wall Carbon Nanotubes
The interlayer distance in MWNTs is closer to the interlayer distance in graphite, which is equal to half of the cell parameter c (0.5c=0.3355 nm). MWNTs show typical diameters of 30-50 nm.
Carbon nanotubes exhibit potentials derived from
a combination of unique dimensional, structural and topological
features. In particular, electronic conductive or semiconductive
behavior, excellent mechanical strength, exceptionally high elastic
properties, large elastic strain, low density, high thermal conductivity,
open pipe framework and relative chemical inertness. These properties
render CNTs ideal materials for use in conventional and high technology
applications, including sensors, microelectronic and semi-conductor
devices, field emission displays, light weight but high-strength
composites, scanning probes, hydrogen storage materials, nanoelectrodes,
sorbents and membrane materials for separations, catalysts, and
energy conversion devices (e.g., fuel cells and batteries).
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